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蓄電池鉛的氧化及水分消失過(guò)程

 

蓄電池固化的基本過(guò)程發(fā)生如下反應(yīng):鉛的氧化.水分消失(極板干燥); 鉛膏中堿式硫酸鉛的重結(jié)晶,板柵表面腐蝕。
① 游離鉛的氧化與板柵表面的腐蝕在極板中游離鉛氧化與板柵表面腐蝕本質(zhì)上這兩個(gè)過(guò)程相同,但它們各自進(jìn)行的速率不一樣。因?yàn)楹辖鹬刑砑佑凶兙⿻?huì)影響板柵的氧化速率。
極板固化時(shí)鉛膏中的水分、游離金屬鉛與固化時(shí)間的關(guān)系。

固化時(shí)由于兩個(gè)過(guò)程的變化速率是互相關(guān)聯(lián)的,水作為一種催化劑,在金屬鉛氧化時(shí)是一個(gè)放熱反應(yīng)。正因?yàn)榉磻?yīng)產(chǎn)生熱,又可將極板中水分從鉛膏里蒸發(fā)出來(lái)。因此鉛膏中水含量與游離鉛的氧化速率有密切關(guān)系。當(dāng)鉛膏中水分含量在7% -8.5%時(shí),這時(shí)的金屬鉛氧化速率最高。
在固化時(shí)鉛膏中保持水含量在8 %左右只有極短的時(shí)間,鉛的氧化過(guò)程可能會(huì)延長(zhǎng)或者它的速率會(huì)達(dá)到最大值。要是鉛膏中最初的水含量在9.5 -10.5 % ,當(dāng)過(guò)程開(kāi)始時(shí),鉛氧化速率一開(kāi)始增大,然后則慢慢地變化,這是因?yàn)殂U膏中水分含量在減少。當(dāng)水分含量達(dá)到8.5%這一值時(shí),氧化速率達(dá)到最大值的特征,若鉛膏中最初的水分含量高于10.5 % 時(shí),需要大量熱能蒸發(fā),促使鉛膏中水分以最快速度減少至8.5%。在該條件下固化一開(kāi)始氧化速度較慢,熱放出也不多,然后只有部分金屬鉛氧化。當(dāng)極板進(jìn)人固化前水分含量太少(低于6 %)時(shí),固化過(guò)程就不能進(jìn)行。因?yàn)橛坞x鉛已經(jīng)氧化,重結(jié)晶過(guò)程也已完成。采用控溫控濕固化室可以解決生極板中水分的合理調(diào)整,固化室內(nèi)濕度的控制與運(yùn)作,要確保生極板氧化反應(yīng)得到最大速度,因此固化室內(nèi)溫度與濕度控制非常重要。固化開(kāi)始前的24h ,鉛的氧化與水的蒸發(fā)都是以較高速率在進(jìn)行,經(jīng)過(guò)24h 后,水與金屬鉛的量基本保持不變。
固化過(guò)程生極板中游離鉛的氧化速率取決于鉛膏中水分含量以及鉛膏在固化室內(nèi)空氣的溫度與濕度以及固化室中空氣的流動(dòng)情況。鉛膏的游離鉛的氧化與鉛粉粒子大小有關(guān),鉛粉本質(zhì)上是由幾微米的粒子表面氧化成的氧化鉛與核是金屬鉛的小顆粒。在和膏時(shí),部分氧化鉛與硫酸反應(yīng)生成了堿式硫酸鉛,還有部分金屬鉛氧化為氧化鉛。因此還留存有15 %一20 環(huán)的金屬鉛,通過(guò)固化,這些金屬鉛會(huì)變?yōu)檠趸U。

The basic process of curing following response: lead oxidation loss of water ( plate drying ); paste of tribasic lead sulfate crystallization, grid surface corrosion.

free lead oxide and grid surface corrosion in plate free lead oxide and grid surface corrosion essentially the two processes of the same, but they are not like the rate. Because the alloy added with crystalloblastic agent will affect the grid oxidation rate.

Plate curing paste in the water, free metal lead and curing time relationship.

When cured because the two processes of change rate are related to each other, water as a catalyst, in lead metal oxide is an exothermic reaction. Because the reaction produces heat, but also can be the plates moisture from evaporating out paste. Therefore higher water content and free lead oxidation rate is closely related to. When the lead paste water content of 7% in -8.5%, when the metal lead oxidation rate maximum.

When cured paste to keep the water content is about 8% only a very short time, oxidation processes of lead may be extended or its rate will reach the maximum value. If the lead paste the initial water content in 9.5%-10.5%, when the process is started, lead oxidation rate first increases, and then slowly changes, this is because the water content in the reduction of lead paste. When the water content of up to 8.5% of the value, the oxidation rate reaches a maximum value of the feature, if the lead paste the initial moisture content is higher than 10.5%, need a large number of thermal evaporation, prompted paste moisture to the fastest speed reduced to 8.5%. In the conditions of curing a slower start oxidation, heat release is not much also, and then only part of the metal oxide of lead. When the plates into the prior to curing water content is too low ( less than 6% ), the curing process can not be. Because the free lead is oxidized, recrystallization process has been completed. The temperature and humidity control of plate curing chamber can be solved in water is reasonable adjust, curing the indoor humidity control and operation, to ensure the plates oxidation to obtain maximum speed, thus curing the indoor temperature and humidity control is very important. Curing before the start of the 24h, lead oxide and water evaporation are at a high rate in, after 24h, water and metal lead content remained basically unchanged.

The curing process of plate free lead oxidation rate depends on the paste paste in moisture content and curing of indoor air temperature and humidity as well as the curing chamber air flow. Paste free lead oxide and lead powder particle size, lead is by nature a few micron particle surface oxidation of lead oxide and lead metal core is small particles. In and cream, part of lead oxide is reacted with sulfuric acid to produce a tribasic lead sulfate and lead oxide, metal parts for lead oxide. It also has retained 15% a ring of 20 metallic lead, through curing, these metal lead into lead oxide.

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